Development of a new combined approach to the synthesis of a cathode material based on a solid solution of the composition Li2CoMn3O8

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Cathode materials based on solid solutions of the composition Li2CoMn3O8 were obtained by a combined method and their characteristics were studied. It was found that Li2CoMn3O8 has high electrochemical properties, which makes it a promising cathode material for lithium-ion batteries, an alternative to LiCoO2. Using X-ray phase analysis and spectrometry, the resulting phases were identified and their chemical composition was determined. Electron microscopy and Brunauer–Emmett–Teller methods were used to study the structure and morphology. A technological scheme for the production of Li2CoMn3O8 has been proposed, which ensures the formation of nano-sized samples with a high specific surface area and improved electrochemical characteristics. The electrochemical properties of the synthesized samples were studied.

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R. Korneykov

Sakhalin State University; Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
俄罗斯联邦, Yuzhno-Sakhalinsk; Apatity

V. Efremov

Sakhalin State University; Institute of North Industrial Ecology Problems Separate subdivision of the Federal State Budgetary Institution of Science of the Federal Research Center “Kola Science Center”

编辑信件的主要联系方式.
Email: v.efremov@ksc.ru
俄罗斯联邦, Yuzhno-Sakhalinsk; Apatity

S. Aksenova

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
俄罗斯联邦, Apatity

K. Kesarev

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
俄罗斯联邦, Apatity

O. Akhmetov

Sakhalin State University

Email: v.efremov@ksc.ru
俄罗斯联邦, Yuzhno-Sakhalinsk

O. Shcherbina

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
俄罗斯联邦, Apatity

I. Elizarova

Institute of North Industrial Ecology Problems Separate subdivision of the Federal State Budgetary Institution of Science of the Federal Research Center “Kola Science Center”

Email: v.efremov@ksc.ru
俄罗斯联邦, Apatity

I. Tananaev

Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre “Kola Science Centre of the Russian Academy of Sciences” Science Centre of Russian Academy of Sciences

Email: v.efremov@ksc.ru
俄罗斯联邦, Apatity

O. Shichalin

Sakhalin State University

Email: v.efremov@ksc.ru
俄罗斯联邦, Yuzhno-Sakhalinsk

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2. Rice. 1. X-ray diffraction patterns of synthesized Li2CoMn3O8 samples: a – ratio Li : Co, Mn = 2.5 : 1, τ = 2.5 h; b – Li : Co, Mn = 2.5 : 1, τ = 1.5 h; c – Li : Co, Mn = 2.23 : 1, τ = 2.5 h; d – Li : Co, Mn = 1.95 : 1, τ = 2.5 h.

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3. Fig. 2. SEM images of Li2CoMn3O8 samples at different magnifications: a – ratio Li:Co,Mn = 2.5:1; b – Li:Co,Mn = 2.23:1.

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4. Fig. 3. IR spectrum of Li2CoMn3O8 obtained at a ratio of Li:Co,Mn = 2.23:1.

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5. Fig. 4. Basic technological scheme for obtaining Li2CoMn3O8.

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6. Fig. 5. Complex impedance diagrams of Li2CoMn3O8 samples synthesized at a ratio of Li:Co,Mn = 2.5:1 (a) and 2.23:1 (b).

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7. Fig. 6. Equivalent circuit.

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