The Preparation of Self-Cleaning Wool-Fiber–TiO2-Pillared Montmorillonite Composites with UV-Protection Properties

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Abstract

Composites of wool fibers with TiO2-pillared montmorillonite are obtained for the first time which possess a property of self-cleaning from substances of organic origin due to the photocatalytic effect. The materials are characterized by X-ray diffraction, IR and UV-Vis spectroscopy, scanning electron microscopy, and low-temperature adsorption–desorption of nitrogen. The self-cleaning properties are studied by way of example of model dyes, methylene blue and rhodamine B. The discoloration of colored composites reaches 95% after 24-h radiation with soft ultraviolet without sacrificing a higher breaking strength of the fibers.

About the authors

N. L. Ovchinnikov

Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

Email: butman@isuct.ru
Россия, 153000, Иваново, просп. Шереметьевский

E. L. Vladimirtseva

Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

Email: butman@isuct.ru
Россия, 153000, Иваново, просп. Шереметьевский

F. A. Bykov

Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

Email: butman@isuct.ru
Россия, 153000, Иваново, просп. Шереметьевский

O. S. Izyumova

Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

Email: butman@isuct.ru
Россия, 153000, Иваново, просп. Шереметьевский

M. F. Butman

Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

Author for correspondence.
Email: butman@isuct.ru
Россия, 153000, Иваново, просп. Шереметьевский

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Copyright (c) 2023 Н.Л. Овчинников, Е.Л. Владимирцева, Ф.А. Быков, О.С. Изюмова, М.Ф. Бутман