Synthesis of micro- and mesoporous aluminosilicates in the presence of polyethylene glycol

Cover Page

Cite item

Full Text

Abstract

Natural and synthetic aluminosilicates currently have a wide range of applications. Silicon-containing wastes of rice production are of great interest as a source of raw materials for their production. The purpose of this work is to synthesize micro- and mesoporous materials from rice husk by templat method using PEG-6000. The obtained samples were investigated by differential thermal analysis and IR spectroscopy, which showed the introduction of PEG into the structure of potassium aluminosilicate during sol-gel synthesis. The specific surface area of the samples and pore size distribution were determined by low-temperature nitrogen adsorption, according to which it was found that the pore radius increased from 100 to 200 Å during sol-gel synthesis when the PEG concentration was changed from 5 to 20 mmol/L. The study of the surface of the samples by scanning electron microscopy showed that the introduction of templat changes their surface morphology and promotes structuring.

Full Text

Restricted Access

About the authors

O. D. Arefieva

Far Eastern Federal University; Institute of Chemistry Far-Eastern Branch of the Russian Academy of Sciences

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok; Vladivostok

S. V. Dovgan

Far Eastern Federal University

Author for correspondence.
Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok

A. V. Kovekhova

Far Eastern Federal University; Institute of Chemistry Far-Eastern Branch of the Russian Academy of Sciences

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok; Vladivostok

A. E. Panasenko

Institute of Chemistry Far-Eastern Branch of the Russian Academy of Sciences

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok

M. A. Tsvetnov

Far Eastern Federal University

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok

A. G. Kozlov

Far Eastern Federal University

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok

K. A. Pervakov

Far Eastern Federal University

Email: dovgan.sv@dvfu.ru
Russian Federation, Vladivostok

References

  1. Hong-Tao L., Jiu-Jiang W., Fang-Ming X. et al. // Pet. Sci. 2023. V. 20. P. 1903. https://doi.org/10.1016/j.petsci.2022.11.028
  2. Nugrahaa R.E., Purnomo H., Aziz A. et al. // S. Afr. J. Chem. Eng. 2024. V. 49. P. 122. https://doi.org/10.1016/j.sajce.2024.04.009
  3. Yanga H., Han T., Yang W. et al. // J. Anal. Appl. Pyrolysis. 2022. V. 165. P. 105536. https://doi.org/10.1016/j.jaap.2022.105536
  4. Singh B.K., Bhadauria J., Tomar R. et al. // Desalination. 2022. V. 268. P. 189. https://doi.org/10.1016/j.desal.2010.10.022
  5. Singh B.K., Tomar R., Kumar S. et al. // J. Hazard. Mater. 2010. V. 178. P. 771. https://doi.org/10.1016/j.jhazmat.2010.02.007
  6. Bhadoria R., Singh B.K., Tomar R. // Desalination. 2010. V. 254. P. 192. https://doi.org/10.1016/j.desal.2009.11.016
  7. Mahinroosta M., Moattari R.M., Allahverdi A. et al. // Circ. Econ. 2024. P. 100100. https://doi.org/10.1016/j.cec.2024.100100
  8. Simancas R., Takemura M., Chen C.-T. // J. Non-Cryst. Solids. 2023. V. 605. P. 122172. https://doi.org/10.1016/j.jnoncrysol.2023.122172
  9. Шульц М.М. // Силикаты в природе и практике человека. 1997. С. 197.
  10. Sembiringa S., Simanjuntak W., Manurung P. et al. // Ceram. Int. 2014. V. 40. P. 7067. http://dx.doi.org/10.1016/j.ceramint.2013.12.038
  11. Darsanasiria A.G.N.D., Matalkahb F., Ramli S. et al. // J. Build. Eng. 2018. V. 19. P. 36. https://doi.org/10.1016/j.jobe.2018.04.020
  12. Simanjuntak W., Sembiring S., Manurung P. et al. // Ceram. Int. 2013. V. 39. P. 9369. http://dx.doi.org/10.1016/j.ceramint.2013.04.112
  13. Филиппова Е.О., Шафигулин Р.В., Виноградов К.Ю. и др. // Сорб. и хром. процессы. 2020. Т. 20. C. 696.
  14. Tretyakov Yu.D., Gudilin E.A. // Int. Sci. J. Alt. Energy Ecol. 2009. V. 6. № 74. C. 39.
  15. Глотов А.П., Ставицкая А.В., Новиков А.А. и др. // XI междунар. конф., посвященная 50-летию Института химии нефти СО РАН. Томск: Изд-во ИОА СО РАН. 2020. 65 с.
  16. Gautier C., Abdoul-Aribi N., Roux C. et al. // Colloids Surf. B: Biointerfaces. 2008. V. 65. № 1. P. 140. https://doi.org/10.1016/j.colsurfb.2008.03.005
  17. Shchipunov Y., Shipunova N. // Colloids Surf. B: Biointerfaces. 2008. V. 63. № 1. P. 7. http://doi.org/10.1016/j.colsurfb.2007.10.022
  18. Beck J.S., Vartuli J.C., Roth W.J. et al. // J. Am. Chem. Soc. 1992. V. 114. № 27. P. 10834. http://doi.org/10.1021/ja00053a020
  19. Casiraghi A., Selmin F., Minghetti P. et al. Nonionic Surfactants: Polyethylene Glycol (PEG) Ethers and Fatty Acid Esters as Penetration Enhancers. In: Dragicevic, N., Maibach, H. (eds) Percutaneous Penetration Enhancers Chemical Methods in Penetration Enhancement. Springer, Berlin, Heidelberg, 2015. https://doi.org/10.1007/978-3-662-47039-8_15
  20. Guo W., Luo G.S., Wang Y.J. et al. // J. Colloid Interface Sci. 2004. V. 207. № 2. P. 400. https://doi.org/10.1016/j.jcis.2003.08.056 - 20
  21. Яцковская О.В., Бакланова О.Н., Гуляева Т.И. и др. // Физикохимия поверхности и защита материалов. 2013. Т. 49. № 2. С. 223.
  22. Chen G., Jiang L., Wang L. et al. // Microporous Mesoporous Mater. 2010. V. 134. № 1-3. P. 189. http://doi.org/10.1016/j.micromeso.2010.05.025
  23. Xu F., Dong M., Gou W. et al. // Microporous Mesoporous Mater. 2012. V. 163. P. 192. http://doi.org/10.1016/j.micromeso.2012.07.030
  24. Li D., Zhu X. // ACS Mater. Lett. 2011. V. 11. P. 1528. http://doi.org/10.1016/j.matlet.2011.03.011
  25. Панасенко А.Е., Борисова П.Д., Арефьева О.Д. и др. // Химия растительного сырья. 2019. № 3. С. 291. http://doi.org/10.14258/jcprm.2019034278
  26. Иконникова К.В., Иконникова Л.Ф., Минакова Т.С. и др. Теория и практика рН-метрического определения кислотно-основных свойств поверхности твердых тел: учебное пособие. Томск: Изд-во Томского политехн. ун-та, 2011.
  27. Карнаухов А.П. Адсорбция. Текстура дисперсных и пористых материалов / Новосибирск: Издательство Сибирского отделения РАН, 1989.
  28. Грег С., Синг К. Адсорбция, удельная поверхность, пористость. Пер. с англ. / М.: Мир, 1984.
  29. Айлер Р.К. Химия кремнезема: растворимость, полимеризация, коллоидные и поверхностные свойства, биохимия. Пер. с англ. М.: Мир, 1982.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Scheme for obtaining potassium aluminosilicate samples in the presence of the structure-controlling agent PEG-6000.

Download (215KB)
Indexing metadata
3. Fig. 2. SEM image of the control sample AL(K)-0.

Download (121KB)
Indexing metadata
4. Fig. 3. SEM images of aluminosilicate samples: a – Al(K)-5; b – Al(K)-5(p).

Download (116KB)
Indexing metadata
5. Fig. 4. SEM images of aluminosilicate samples: a – Al(K)-10; b – Al(K)-10(p).

Download (97KB)
Indexing metadata
6. Fig. 5. SEM images of aluminosilicate samples: a – Al(K)-20; b – Al(K)-20(p).

Download (101KB)
Indexing metadata
7. Fig. 6. Nitrogen adsorption–desorption isotherm at 77 K for the control sample Al(K)-0.

Download (50KB)
Indexing metadata
8. Fig. 7. Nitrogen adsorption–desorption isotherms at 77 K for aluminosilicate samples: a – Al(K)-5; b – Al(K)-5(p).

Download (113KB)
Indexing metadata
9. Fig. 8. Nitrogen adsorption–desorption isotherms at 77 K for aluminosilicate samples: a – Al(K)-10; b – Al(K)-10(p).

Download (100KB)
Indexing metadata
10. Fig. 9. Nitrogen adsorption–desorption isotherms at 77 K for aluminosilicate samples: a – Al(K)-20; b – Al(K)-20(p).

Download (100KB)
Indexing metadata
11. Fig. 10. Differential curve of pore volume distribution by radius of the Al(K)-0 sample.

Download (58KB)
Indexing metadata
12. Fig. 11. Differential curves of pore volume distribution by radius of potassium aluminosilicate samples: a – Al(K)-5; b – Al(K)-10; c – Al(K)-20.

Download (138KB)
Indexing metadata
13. Fig. 12. Differential curves of pore volume distribution by radius of potassium aluminosilicate samples: a – Al(K)-5(p); b – Al(K)-10(p); c – Al(K)-20(p).

Download (143KB)
Indexing metadata
14. Fig. 13. Integral curves of mass loss of potassium aluminosilicate samples.

Download (176KB)
Indexing metadata
15. Fig. 14. Differential curves of temperature change of potassium aluminosilicate samples.

Download (181KB)
Indexing metadata
16. Fig. 15. IR spectra of potassium aluminosilicate samples: 1 – Al(K)-0; 2 – Al(K)-5(p); 3 – Al(K)-10(p); 4 – Al(K)-20(p).

Download (193KB)
Indexing metadata
17. Fig. 16. IR spectra of potassium aluminosilicate samples: 1 – Al(K)-5; 2 – Al(K)-10; 3 – Al(K)-20.

Download (156KB)
Indexing metadata

Copyright (c) 2025 Russian Academy of Sciences