INVESTIGATION OF THE PHOSPHATE IONS ADSORPTION FROM ALUMINATE SOLUTIONS BY Fe-AС NANOCOMPOSITE

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription or Fee Access

Abstract

The adsorption of phosphate ions from model solutions by a nanocomposite based on trivalent iron oxide-hydroxide and activated carbon (Fe-AС) was studied. Factors studied affecting the adsorption of phosphate ions: solution pH; adsorbent amount; initial concentration of phosphate ions in solution; contact duration. The efficiency of phosphate ion extraction increased with increasing adsorbent dosage (from 2.5 to 10 g/l) with an initial concentration of phosphate ions of 0.1 g/l. Adsorption is well described by the Langmuir and Frendlich isotherms. The results of the work showed that the Fe-AС nanocomposite has a good potential for adsorption of phosphate ions from aluminate solutions, which was confirmed by SEM/EDS analysis.

About the authors

A. A Geydarov

Nagiev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of Azerbaijan, Baku, Azerbaijan

Email: arif.heyderov.54@mail.ru

P. G Babaeva

Nagiev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of Azerbaijan, Baku, Azerbaijan

Email: eliz@imet.ac.ru

A. A Gulieva

Nagiev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of Azerbaijan, Baku, Azerbaijan

Email: eliz@imet.ac.ru

G. I Alyshanly

Nagiev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of Azerbaijan, Baku, Azerbaijan

Email: eliz@imet.ac.ru

Z. A Dzhabbarova

Nagiev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of Azerbaijan, Baku, Azerbaijan

Author for correspondence.
Email: eliz@imet.ac.ru

References

  1. Демьяненко, А.И. Очистка алюминатных растворов от соединений фосфора, ванадия и фтора / А.И. Демьяненко, О.C.Балак, В.Н. Балак // Цв. металлы. 1967. №1. С.61-63.
  2. Романов, Л.Г. Очистка алюминатных растворов от примесей фосфора и ванадия / Л.Г. Романов, Б.Ш. Джумбаев, Л.П. Ни // Тр. ИМО АН Каз. ССР. 1970. Т.ХХХVII. С.26-31.
  3. Onakonak, А.K. Phosphates removal by activated carbon / А.K. Onakonak, L. Youcef // Sensor Letters. 2016. V.14. №6. P.600-605.
  4. Kumar, P. Phosphate removal from aqueons solution using coir-pith activated carbon / P. Kumar, S. Sudha, S. Chanq, V.C. Srivastavd // Separation Sci. Technol. 2010. V.45. P.1463-1470.
  5. Le, Z. Adsorptive removal of phosphate from aqueous solutions using iron oxide tailings / Z. Le, L. Xiaomei, L. Jindun // Water Research. 2004. V.38. P.1318-1326.
  6. Shivkumar, S.P. Removal of phosphate vsing red mud: an environmentally hazardous waste by-product of alumina industry / S.P. Shivkumar, P.A.M. Najar, Y.M. Tangde // Advances in Physical Chemistri. - Hindawi Publ. Corp. 2016. V.16. Art.9075206.
  7. Орлов, С.Н. Адсорбция фосфат-ионов из водных растворов на красном шламе / С.Н. Орлов, К.А. Бурков, М.Ю. Скрипкин // Вода: Химия и экология. 2013. №12. С.104-107.
  8. Kim, J. Phosphate adsorption on the iron oxyhyddes goethite (a-FeOOH), akaganeite (b-FeOOH), lepidocrocite (g-FeOOH) /j. Kim, W. Li, B.L. Philips, C.P. Grey // Energy and Environmental Science. 2011. V.4. №10. P.4298-4305.
  9. Namasivayam, C. Recycling Fe(lll)/Cr(lll) hydrokide, an industrial solid waste for the removal of phosphate from water / C. Namasivayam, K. Prathap //j. Hazard. Mater. 2005. V.123. P.127-134.
  10. Tanada, S. Removal of phosphate by aluminium oxide hidrokside / S. Tanada, M. Kabayama, N. Kawasaki, T. Sakiyama, T. Nakamura, M. Azaki, T. Tamura //j. Colloid Interf. Sci. 2003. V.257. P.135-140.
  11. Wang, K. Mutual efforts of cadmium and phosphate on their adspoption and desorption by goethite / K. Wang, B. Xing // Environ. Pollut. 2004. V.127. P.13-20.
  12. Qiaoling, X. Phosphorus removal from aqueous solution by adsorption using Wetlang-based biochar: Bath experiment / X. Qiaoling, W. Li, T. Minxia, W. Xiaolei, L. Siajie, C. Hejun // Green Processing and Synthesis. 2022. №11. P.555-562.
  13. Sharififard, H. Performance comparision of activated karbon and ferric oxide-hydrokside-activated carbon nanocomposite as vanadium (V) ion adsorbents / H. Sharififard, M. Soleimani // Royal Soc. Chem. 2015. V.5(98). P.80650-80660.
  14. Zhu, H. Removal of arsenic from water by supported nano zero-valent iron on activated carbon / H. Zhu, Y. Jia, X. Wu, H.J. Wang // Hazard. Mater. 2009. V.172. №2-3. P.1591-1596.
  15. Mehrabi, N. Parametr optimization for nitrate removal from water using activated carbon and Fe2O3 nanopartroles / N. Mehrabi, M. Soleimani, M. Yeganeh, H. Shariffard // RSC Advanc. 2015. V.5. P.51470-51482.
  16. Османова, А.Х. Исследование адсорбции ванадия (V) из алюминатных растворов нанокомпозитом Fe-AУ / А.Х. Османова, А.А. Гейдаров, З.А. Джаббарова, Г.И. Алышанлы // Металлы. 2022. №2. С.28-33.
  17. A.Kh. Osmanova, A.A. Geidarov, Z.A. Dzhabbarova, G.I. Alyshanly. "Vanadium (V) adsorption from aluminate solutions by an Fe-AC nanocomposite".Russian Metallurgy (Metally). 2022. №3. P.211-216.
  18. Пат.RU2045477. МПК: С1. Способ переработки ванадиевого концентрата глиноземного производства / Равдоникас И.В., Насыров Г.З., Кравцова Е.Г.; заявитель: АООТ "Всероссийский алюминиево-магниевый институт"; заявл. 06.08.1992; опубл. 10.10.1995.
  19. Boddu, V.M. Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent / V.M. Boddu, K. Abburi, I.L. Talbott, E.D. Smith // Environment Sci. Technol. 2003. V.37. Р.4449-4456.
  20. Chitrackar, R. Phosphate adsorption on synthetic goethite and akagainneite / R. Chitrackar, S. Tezuka, A. Sonada //j. Colloid and Interface Sci. 2006. V.298. P.602-608.

Supplementary files

Supplementary Files
Action
1. JATS XML

Copyright (c) 2023 Russian Academy of Sciences