Optimization of hydrothermal synthesis of pharmacosiderite-type titanosilicates for extraction of 137Cs and 90Sr from liquid media with high salinity

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Abstract

The paper presents the synthesis of and the influence of the duration of hydrothermal synthesis on the sorption properties of pharmacosiderite type titanosilicates towards Cs(I) and Sr (II), structural phase composition, surface morphology and textural characteristics is investigated. The composition, morphology and structure of the samples were studied by XRF, SEM, and EMF methods. The structural characteristics of powders have been studied by BET and DFT methods. The sorption properties towards the radionuclide 137Cs in micro-concentration under adsorption conditions from model solutions of low and medium concentration of interfering impurities are investigated for the first time for disubstituted pharmacosiderite-type titanosilicates.

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About the authors

P. A. Marmaza

Far Eastern Federal University; Sakhalin State University

Author for correspondence.
Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok; Yuzhno-Sakhalinsk

N. P. Ivanov

Far Eastern Federal University

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok

V. O. Kaptakov

Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: marmaza.pa@dvfu.ru
Russian Federation, Moscow

Ya. G. Zernov

Far Eastern Federal University

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok

V. Y. Mayorov

Far Eastern Federal University; Far Eastern Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok; Vladivostok

A. N. Fedorets

Far Eastern Federal University

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok

O. O. Shichalin

Far Eastern Federal University; Sakhalin State University

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok; Vladivostok

E. K. Papynov

Far Eastern Federal University

Email: marmaza.pa@dvfu.ru
Russian Federation, Vladivostok

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Supplementary files

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2. Fig. 1. Diffraction patterns of the obtained samples.

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3. Fig. 2. SEM images of the sample surface and EDS maps of the elemental distribution.

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4. Fig. 3. Low-temperature nitrogen adsorption–desorption isotherms and pore size distribution according to the DFT model (a – GTS-1; b – GTS-2; c – GTS-3; d – GTS-4).

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